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The Preservation of Antiquities

Friedrich Rathgen

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Book Excerpt: 
. . . copper carbonate has been shown by the examination made by Dr Wibel to be a product of the reduction of copper carbonate by the metallic copper of the bronze. Bronzes belonging to this category have often lost their former metallic properties, and if of small diameter have often been completely converted into cuprous oxide, surrounded by a lustrous green or blue crust of carbonates. If a metallic core remains, it is found to be crystalline, brittle, and non-coherent, that is, it flies to pieces under the blow of a hammer. Fine ornamentation and sharpness, whether of edge or of point, have often disappeared. This does not occur with bronzes preserved in water.”

[17] In another volume of the series[28] von Fellenberg states that basic copper chloride occurs as a constituent of patina.

A few lengthier quotations may be conveniently given here, in part verbatim, in part abstracted from literature which is not readily accessible. Read More